Concentration Converter

Convert between molarity, molality, ppm, ppb, mass percent, and more

Concentration Unit Definitions

Molarity (M)

M = moles solute / L solution

Temperature-dependent (solution volume changes with T)

Molality (m)

m = moles solute / kg solvent

Temperature-independent (mass doesn't change)

Mass Percent (%)

% = (mass solute / mass solution) × 100

Parts Per Million (ppm)

ppm = (mass solute / mass solution) × 10⁶

For dilute aqueous solutions: 1 ppm ≈ 1 mg/L

Parts Per Billion (ppb)

ppb = (mass solute / mass solution) × 10⁹

For dilute aqueous solutions: 1 ppb ≈ 1 μg/L

Mole Fraction (χ)

χA = moles A / total moles

Dimensionless, sum of all χ = 1

Normality (N)

N = equivalents solute / L solution

N = M × n (where n = # of H⁺, OH⁻, or charge)

Conversion Formulas

Molarity ↔ Molality

M → m:

m = (M × 1000) / (ρsoln × 1000 - M × MMsolute)

m → M:

M = (m × ρsoln × 1000) / (1000 + m × MMsolute)

ρsoln = solution density (g/mL), MM = molar mass (g/mol)

Molarity → ppm

ppm = M × MMsolute

(For dilute aqueous solutions where ρ ≈ 1 g/mL)

Mass Percent → Molarity

M = (% × ρsoln × 10) / MMsolute

ρsoln in g/mL, % as decimal (e.g., 10% = 0.10)

ppm ↔ ppb

1 ppm = 1000 ppb
ppb = ppm × 1000

Worked Examples

Example 1: Molarity to Molality

Problem: Convert 2.0 M NaCl solution (density = 1.08 g/mL) to molality.

Solution:

MM(NaCl) = 58.44 g/mol

m = (M × 1000) / (ρ × 1000 - M × MM)

m = (2.0 × 1000) / (1.08 × 1000 - 2.0 × 58.44)

m = 2000 / (1080 - 116.88)

m = 2000 / 963.12

m = 2.08 mol/kg

Example 2: Mass Percent to Molarity

Problem: Calculate molarity of 10% (w/w) H₂SO₄ solution (density = 1.07 g/mL).

Solution:

MM(H₂SO₄) = 98.08 g/mol

% = 10% = 0.10

M = (% × ρ × 10) / MM

M = (0.10 × 1.07 × 10) / 98.08

M = 1.07 / 98.08

M = 1.09 M

Example 3: Molarity to ppm

Problem: Convert 0.001 M Ca²⁺ to ppm.

Solution:

MM(Ca) = 40.08 g/mol

ppm = M × MM

ppm = 0.001 mol/L × 40.08 g/mol

ppm = 0.04008 g/L = 40.08 mg/L

40.1 ppm Ca²⁺

Quick Reference Table

UnitSymbolDefinitionUse Case
MolarityMmol/LReactions, titrations
Molalitymmol/kgColligative properties
Mass %%(g/g) × 100Commercial solutions
ppmppm(mg/kg) or (mg/L)Environmental, trace
ppbppb(μg/kg) or (μg/L)Ultra-trace analysis

Common Mistakes

⚠️

Confusing Molarity and Molality

M uses L of solution, m uses kg of solvent!

⚠️

Wrong Density Units

Density must be in g/mL for these formulas!

⚠️

ppm Assumptions

ppm ≈ mg/L only for dilute aqueous solutions!

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Pro Tip

Always check if you need mass of solvent or solution!