Normality Formula

Express solution concentration as equivalents per liter

Definition

N = equivalents of solute / liters of solution

Variables

  • N = normality (eq/L)
  • equivalents = moles × n-factor
  • V = volume of solution (L)
  • n-factor = reactive capacity per mole (acid/base/redox)

Quick Uses

  • Acid-base titrations with polyvalent species
  • Redox reactions using equivalents of electrons
  • Precipitation reactions with ionic charge balance

How to Calculate

  1. Identify the reaction and determine the n-factor (protons, electrons, or charge exchanged).
  2. Compute equivalents = moles of solute × n-factor.
  3. Measure or convert solution volume to liters.
  4. Divide equivalents by liters to get N (eq/L).

For acids/bases: n-factor = number of H+ donated/accepted per formula unit. For redox: n-factor = electrons transferred per formula unit.

Worked Example

Problem: Find the normality of 0.50 M H2SO4 for an acid-base titration (assume both protons react).

1) n-factor for H2SO4 = 2 (two acidic hydrogens).

2) Equivalents per liter = 0.50 mol/L × 2 = 1.00 eq/L.

3) Normality N = 1.00 eq/L.

Answer: 1.00 N

Common Pitfalls

Wrong n-factor

Match n-factor to the actual reaction stoichiometry, not just the formula.

Volume units

Use liters, not mL; divide by 1000 if needed.

Assuming full dissociation

Polyprotic acids may donate fewer protons depending on pH and reaction context.

Mixing M and N

Normality depends on reaction; 1 M is not always 1 N.

Related Calculators

FAQ

Is normality still commonly used?

It appears in titration contexts, but molarity is generally preferred. Use N when equivalents simplify calculations.

How do I find n-factor in redox?

Balance the half-reaction and count electrons transferred per formula unit.

Can I convert between M and N?

Yes: N = M × n-factor for the specific reaction.