Calculate molecular velocities and kinetic energies using kinetic molecular theory
Root-Mean-Square Velocity: vrms = √(3RT/M)
Calculate molecular velocities and kinetic energies from temperature
m/s
K
g/mol
Kinetic Molecular Theory explains gas behavior at the molecular level, relating temperature to the average kinetic energy of gas molecules.
vrms = √(3RT/M)
Most Probable: vp = √(2RT/M)
Average: vavg = √(8RT/πM)
RMS: vrms = √(3RT/M)
vrms > vavg > vp
| Gas | M (g/mol) | vrms (m/s) | vrms (km/h) |
|---|---|---|---|
| H₂ | 2.02 | 1927 | 6937 |
| He | 4.00 | 1363 | 4907 |
| H₂O (steam) | 18.02 | 643 | 2315 |
| N₂ | 28.01 | 515 | 1854 |
| O₂ | 32.00 | 482 | 1735 |
| Ar | 39.95 | 431 | 1552 |
| CO₂ | 44.01 | 411 | 1480 |
Note: These are extremely fast speeds! Faster than the speed of sound (~343 m/s at 20°C).
Gas molecules are point masses with negligible volume compared to container volume.
Molecules are in constant, random, straight-line motion.
Collisions are perfectly elastic (no energy lost).
No attractive or repulsive forces between molecules (except during collisions).
Average kinetic energy is directly proportional to absolute temperature: KE = (3/2)kBT