Boiling Point Elevation Calculator

Boiling Point Elevation Calculator

Boiling Point Elevation Formula

ΔTb = i × Kb × m

Non-electrolytes: i = 1 | NaCl, KCl: i ≈ 2 | CaCl₂, MgSO₄: i ≈ 3

Common Kb Values (°C·kg/mol):

Water: 0.512
Benzene: 2.53
Ethanol: 1.19
Chloroform: 3.63
Acetic acid: 3.07
Cyclohexane: 2.79

What This Calculator Does

The Boiling Point Elevation Calculator determines how much a solvent's boiling point increases when a non-volatile solute is dissolved in it. This is one of the four colligative properties of solutions, meaning it depends only on the concentration of solute particles, not their identity.

When you add salt to water, sugar to water, or any non-volatile solute to a solvent, the boiling point rises. This calculator uses the formula ΔTb = Kb × m × i to calculate this elevation, where:

  • ΔTb - Boiling point elevation (temperature increase in °C or K)
  • Kb - Ebullioscopic constant (specific to each solvent)
  • m - Molality of the solution (mol solute/kg solvent)
  • i - Van't Hoff factor (number of particles per formula unit)

Formula & Calculation Method

Core Formula

ΔTb = Kb × m × i

Where:

  • ΔTb = Boiling point elevation (°C)
  • Kb = Ebullioscopic constant (°C·kg/mol)
  • m = Molality (mol/kg)
  • i = Van't Hoff factor (dimensionless)

Common Kb Values:

Water: 0.512 °C·kg/mol

Benzene: 2.53 °C·kg/mol

Ethanol: 1.22 °C·kg/mol

Chloroform: 3.63 °C·kg/mol

Van't Hoff Factor (i):

Non-electrolytes (sugar, urea): i = 1

NaCl: i ≈ 2 (Na⁺ + Cl⁻)

CaCl₂: i ≈ 3 (Ca²⁺ + 2Cl⁻)

Al₂(SO₄)₃: i ≈ 5 (2Al³⁺ + 3SO₄²⁻)

Step-by-Step Example

Problem: What is the boiling point of a solution made by dissolving 58.5 g of NaCl in 1.00 kg of water?

Step 1: Calculate molality

Molar mass of NaCl = 58.5 g/mol

Moles = 58.5 g ÷ 58.5 g/mol = 1.00 mol

m = 1.00 mol ÷ 1.00 kg = 1.00 m

Step 2: Identify constants

Kb (water) = 0.512 °C·kg/mol

i (NaCl) = 2 (dissociates into Na⁺ and Cl⁻)

Step 3: Calculate ΔTb

ΔTb = 0.512 × 1.00 × 2 = 1.024 °C

Step 4: Find new boiling point

Normal BP of water = 100.0 °C

New BP = 100.0 + 1.024 = 101.024 °C

Real-World Applications

🍳 Cooking

Adding salt to water increases boiling point, cooking pasta slightly faster. At high altitudes, lower atmospheric pressure decreases boiling point.

🚗 Automotive

Antifreeze solutions raise the boiling point of engine coolant, preventing overheating in summer while lowering freezing point in winter.

🔬 Laboratory

Determine molecular mass of unknown substances by measuring boiling point elevation. Used in physical chemistry experiments.

🏭 Industry

Process control in chemical manufacturing. Desalination plants use boiling point differences for water purification.

Quick Reference

Units

°C, mol/kg

Formula

ΔTb = Kb × m × i

Applications

Cooking, automotive

Level

College chemistry

Where It's Used

🍳

Culinary

Salt water cooking

🚗

Automotive

Engine coolant

🔬

Research

Molecular mass determination

🏭

Industry

Process control